唐勇课题组

A highly efficacious photoinduced reversible complexation-mediated polymerization (photo-RCMP) system using amino alcohol N-oxide as the catalyst has been developed, allowing access to controlled high-molecular-weight polymers of different methacrylates (Mn = 497–815 kg/mol, ? < 1.5), which is very challenging for those known catalytic...

A facile method for the construction of the aspidosperma core from indole functionalized with a nonterminal N -allenamides and dimethyl methylenemalonate is described. Various polysubstituted tetracyclic spiroindolines (27 examples) were afforded in good yields (61-90%) with >99:1 dr and >99:1 Z/E selectivity under mild conditions.

In this review, we summarize in detail the research on RCMP in the last ten years since its birth, mainly focusing on the development and evolution of catalytic systems, photo-induced RCMP and the special applications derived from their inherent characteristics.