唐勇课题组

2019 年 12 月 9 日，英国皇家化学会联合清华大学举办的首届新星学术论坛在清华大学化学馆 301 涌泉报告厅召开。参加此次论坛的有清华大学化学系王训教授、英国皇家化学会中国和东亚区总经理陈会丽女士、多位学术界资深专家以及来自全国40 所高校的150 余名学生。上海有机所唐勇课题组的周立同学脱颖而出，荣获口头报告三等奖。恭喜周立！

A highly diastereoselective copper‐catalyzed multicomponent cyclization of exocyclic enol ethers/enamines with methylene malonate and aldehydes has been developed to furnish spiroheterocyclic tetrahydropyrans in high yields with greater than 95:5 d.r. This method is practical, in that 36 examples, including a range of aldehydes and exo‐...

20年风雨兼程，敢问路在何方，路在脚下！

? Controlled ATRP of styrene type monomers were achieved at low temperatures.
? ATRP of 4-MeOSt provided polymers rather than oligomers.
? Stereospecificity of polystyrene was gradually enhanced by lowering the temperature.
?A series of novel SaBOX ligands exhibited high activity at low temperature.

A series of fluorinated polyolefins has been efficiently synthesized via the copolymerization of ethylene with 5-(perfluoro-n-alkyl)norbornenes by employing a class of [ONS] titanium catalysts, which possess an open coordination space environment and exhibited excellent tolerance to fluorine atom and excellent catalytic activity (up to 1....

A new regioselective method for the synthesis of multifunctionalized indoles from [3 + 2] annulation of 2-bromocyclopropenes with anilines has been developed. By employing a nickel complex as a catalyst, 27 examples of indole products were obtained in good yields with excellent regioselectivity. Synthetic utility of the resulting product ...